Chemical systems

The fertiliser industry

Haber, Ostwald, contact process. NPK. Eutrophication. Why a catalyst and moderate temperature.

CAPS

Grade 12 · Physical Sciences (Chemistry) · Chemical systems

Chemistry is Physical Sciences Paper 2.

  • The paper

    Grade 12 Paper 2 covers quantitative chemistry, energy and rates, chemical equilibrium, acids and bases, electrochemical cells, and organic nomenclature, reactions and polymers.

  • Working

    Balance before you use a mole ratio. Show n = mM or c = nV with units. An IUPAC name needs the number on the functional group. A reaction that is not balanced cannot support a stoichiometric answer.

  • The relation

    N₂ + 3 H₂ ⇌ 2 NH₃. Haber process

  • How a marker reads it

    Write “compromise between rate and yield”. Leaving out that sentence is the most common fertiliser-question miss.

Paper 2 is 150 marks. Tables of ions and the data sheet are part of the exam. Significant figures follow the data you were given.

Diagram

Worked example

Why does Haber use ~450 °C even though the reaction is exothermic (low T would favour yield)?

Simplified approach

Low T gives more NH₃ but the rate is too slow for a factory. 450 °C is a compromise: decent yield, useful rate, plus an iron catalyst.

Culture note

Maize on a Limpopo smallholding lives on Haber ammonia turned into ammonium nitrate — yield vs rate is a factory decision.

Formulas

N₂+3 H₂ ⇌ 2 NH₃

Haber process

Exam tricks you must know

These are the moves markers look for — not shortcuts that skip the method, but the habits that earn the method mark.

  • Never write “the catalyst increases yield” — that sentence loses the mark in every province

    How:A catalyst speeds both the forward and reverse rates equally. Equilibrium is reached faster; the yield (position of equilibrium) does not change. Write: “increases rate, yield unchanged.” On Haber, add the compromise sentence: rate versus yield.

    When to use it:Rates, equilibrium, Haber and Contact processes.

  • Never change a subscript to balance — only coefficients

    How:The given formula is a substance. Fe₂O₃ is not FeO. Count atoms on each side. Put a number in front (coefficient) until both sides match. Changing a subscript invents a different compound and zeros the question.

    When to use it:Balancing equations and mole-ratio questions.

  • pH to two decimals, with −log and square brackets — “it is strong because pH is 2” is a trap

    How:Write pH = −log[H₃O⁺] as the formula line. Substitute the concentration with a division line if you had to convert cm³. Box the answer to two decimal places. Strength is about complete ionisation, not the pH number alone.

    When to use it:Strong/weak acids, K_w, and titration pH.

Step 1 / 5

Le Chatelier on T

Exothermic: low T favours products. A fridge-cold factory would make more NH₃ — too slowly to sell.

Diagram
Diagram

Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

More worked examples

Board walkthroughs on this topic. Open one, copy the working, then try the next.

Example 1 / 20

A bag contains 80 g of ammonium nitrate, NH₄NO₃. M = 80 g·mol⁻¹ and each mole contains 28 g of nitrogen. What mass of nitrogen is in the bag?

4. Step-by-step working

  1. 01

    Divide

    n=8080=1 mol.

    8080=1
  2. 02

    Multiply

    Nitrogen=1×28=28 g.

    1×28=28

How we got there

Read this like a teacher at the board. We go slowly, name every number, and say why we take each step.

Explain in another language · 11

1. What is the question asking?

Read the question twice. Circle the unknown. Underline every number and unit. The paper is asking: A bag contains 80 g of ammonium nitrate, NH₄NO₃. M = 80 g·mol⁻¹ and each mole contains 28 g of nitrogen. What mass of nitrogen is in the bag?

Before any working — hunt first

Given

Numbers and units already in the sentence: 80 g · 80 g·mol⁻¹ · 28 g. Copy each one into a column. A name without a number is not given.

Missing

After you copy the given, the letter that still has no number is missing. The paper is pointing at: What mass of nitrogen is in the bag. Circle that word — that is the missing variable.

Find

We are required to find: What mass of nitrogen is in the bag. Write that as a symbol on the left, with a question mark, before you touch a formula.

Calculate

Write 8080=1 with empty letters. Cross out every letter that already has a number. Calculate the letter that is still standing — that gives What mass of nitrogen is in the bag.

In other words — as if you have never seen this before

If you have never seen this before: Find how many moles are in the bag, then multiply by the mass of nitrogen in one mole. We will name a method in words, write the formula with no numbers, then substitute one line at a time.

2. What do we already know?

m=80 g, M=80 g·mol⁻¹, nitrogen per mole=28 g.

3. Which method — and why this one?

Find how many moles are in the bag, then multiply by the mass of nitrogen in one mole.

4. Step-by-step working

  1. 01 / 05

    Divide

    n=8080=1 mol.

    8080=1

    Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

  2. 02 / 05

    Multiply

    Nitrogen=1×28=28 g.

    1×28=28

    Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

  3. 03 / 05

    Sense-check

    One mole of NH₄NO₃ contributes 28 g of N, not 2 g. The 14 is the molar mass of nitrogen.

    28 g

    Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

  4. 04 / 05

    Step F — Box the answer with its unit

    28 g of nitrogen

    Why this step: A number without a unit is half a mark on a Physics paper, and a marker can miss a Maths answer that is buried in working.

  5. 05 / 05

    Step H — What the marker is looking for

    On an NSC memo you usually earn: (1) a method mark for naming the right formula or idea in words, (2) an accuracy mark for substituting the given numbers with units, (3) an accuracy mark for the boxed answer with its unit. Write those three lines even if you are unsure of the arithmetic — blank pages score zero.

    Why this step: First-timers chase the final number and leave the method blank. The memo still pays out for the idea and the substitution even when the last line is wrong.

5. The answer

28 g of nitrogen

Copy onto your answer sheet — in this order

Formula: 8080=1

Answer: 28 g of nitrogen

6. Check it like a marker

Counting atoms and forgetting that each nitrogen atom has mass 14 gives a mass that is 14 times too small.

7. A trap first-timers fall into

First-timers often grab the first formula they remember, mix units (cm with m, minutes with seconds), or drop a minus sign. Write the formula in words first: “this equals that, because…”

Ntsako · fx-991ZA PLUS. Tap to calculate.