Chemical change

Energy and chemical change

Exothermic vs endothermic. Bond energy. ΔH negative means heat is released.

CAPS

Grade 11 · Physical Sciences (Chemistry) · Chemical change

Chemistry is Physical Sciences Paper 2.

  • The paper

    Grade 11 Paper 2 covers the mole, concentration, stoichiometry, energy change, types of reaction, and the start of chemical systems.

  • Working

    Balance before you use a mole ratio. Show n = mM or c = nV with units. An IUPAC name needs the number on the functional group. A reaction that is not balanced cannot support a stoichiometric answer.

  • The relation

    ΔH < 0 exothermic ΔH > 0 endothermic. Sign of enthalpy change

  • How a marker reads it

    Do not say “ΔH is exothermic”. ΔH is a number. The reaction is exothermic.

Paper 2 is 150 marks. Tables of ions and the data sheet are part of the exam. Significant figures follow the data you were given.

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Diagram

Worked example

A Firelighter on a Joburg braai: C + O₂ → CO₂, ΔH = −394 kJ·mol⁻¹. Exo or endo? What does the minus mean?

Before any working — hunt first

Given

Numbers and units already in the sentence: 394 kJ·mol⁻¹. Copy each one into a column. A name without a number is not given.

Missing

After you copy the given, the letter that still has no number is missing. The paper is pointing at: What does the minus mean. Circle that word — that is the missing variable.

Find

We are required to find: What does the minus mean. Write that as a symbol on the left, with a question mark, before you touch a formula.

Calculate

Write ΔH < 0 exothermic ΔH > 0 endothermic with empty letters. Cross out every letter that already has a number. Calculate the letter that is still standing — that gives What does the minus mean.

Simplified approach

Minus means the system lost energy to the surroundings as heat. Exothermic. The charcoal gets hot.

Culture note

A township braai is the textbook exothermic reaction — you feel the heat because ΔH is negative.

Formulas

ΔH < 0exothermicΔH > 0endothermic

Sign of enthalpy change

Exam tricks you must know

These are the moves markers look for — not shortcuts that skip the method, but the habits that earn the method mark.

  • Never change a subscript to balance — only coefficients

    How:The given formula is a substance. Fe₂O₃ is not FeO. Count atoms on each side. Put a number in front (coefficient) until both sides match. Changing a subscript invents a different compound and zeros the question.

    When to use it:Balancing equations and mole-ratio questions.

Step 1 / 5

Read the sign

ΔH = −394 kJ·mol⁻¹. The minus is the whole story.

Worked example
ΔH < 0

Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

More worked examples

Board walkthroughs on this topic. Open one, copy the working, then try the next.

Example 1 / 20

0.20 kg of water is heated from 25 °C to 75 °C. Take c = 4 200 J·kg⁻¹·°C⁻¹. Calculate the heat transferred to the water, and say whether this change for the water is endothermic or exothermic.

4. Step-by-step working

  1. 01

    Subtract

    ΔT = 75 − 25 = 50 °C. Use the change, not the starting temperature.

    75−25=50
  2. 02

    Write the formula

    Q = mcΔT. Mass must stay in kilograms because c is per kilogram.

    Q=mcΔT
  3. 03

    Multiply

    0.20 × 4 200 = 840. That is the heat for a 1 °C rise.

    0.20×4 200=840
  4. 04

    Multiply

    840×50=42 000 J.

    840×50=42 000

How we got there

Read this like a teacher at the board. We go slowly, name every number, and say why we take each step.

Explain in another language · 11

1. What is the question asking?

Read the question twice. Circle the unknown. Underline every number and unit. The paper is asking: 0.20 kg of water is heated from 25 °C to 75 °C. Take c = 4 200 J·kg⁻¹·°C⁻¹. Calculate the heat transferred to the water, and say whether this change for the water is endothermic or exothermic.

In other words — as if you have never seen this before

If you have never seen this before: Q = mcΔT. The temperature change is final minus initial. Heat entering the water is endothermic for the water. We will name a method in words, write the formula with no numbers, then substitute one line at a time.

2. What do we already know?

m=0.20 kg, T₁=25 °C, T₂=75 °C, c=4 200.

3. Which method — and why this one?

Q = mcΔT. The temperature change is final minus initial. Heat entering the water is endothermic for the water.

4. Step-by-step working

  1. 01 / 07

    Subtract

    ΔT = 75 − 25 = 50 °C. Use the change, not the starting temperature.

    75−25=50

    Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

  2. 02 / 07

    Write the formula

    Q = mcΔT. Mass must stay in kilograms because c is per kilogram.

    Q=mcΔT

    Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

  3. 03 / 07

    Multiply

    0.20 × 4 200 = 840. That is the heat for a 1 °C rise.

    0.20×4 200=840

    Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

  4. 04 / 07

    Multiply

    840×50=42 000 J.

    840×50=42 000

    Why this step: We only do one job per line so a marker can follow the marks — and so you can find a slip without starting over.

  5. 05 / 07

    Step G — Sense-check the size

    Ask: is this the kind of number a Grade 10–12 paper would want? A speed of 3 000 ms for a learner walking, or a probability bigger than 1, means a unit or algebra slip. Estimate first: round the numbers and do the sum in your head.

    Why this step: Markers write ‘unrealistic’ in the margin when the method is right but the size is wild. A 10-second head check often finds a missing 10² or a unit that never changed.

  6. 06 / 07

    Step F — Box the answer with its unit

    42 000 J, endothermic for the water.

    Why this step: A number without a unit is half a mark on a Physics paper, and a marker can miss a Maths answer that is buried in working.

  7. 07 / 07

    Step H — What the marker is looking for

    On an NSC memo you usually earn: (1) a method mark for naming the right formula or idea in words, (2) an accuracy mark for substituting the given numbers with units, (3) an accuracy mark for the boxed answer with its unit. Write those three lines even if you are unsure of the arithmetic — blank pages score zero.

    Why this step: First-timers chase the final number and leave the method blank. The memo still pays out for the idea and the substitution even when the last line is wrong.

5. The answer

42 000 J, endothermic for the water.

Copy onto your answer sheet — in this order

Formula: 75−25=50

Answer: 42 000 J, endothermic for the water.

6. Check it like a marker

Using 25 or 75 as ΔT, or leaving the mass in grams without changing c, gives the wrong size. The sign of the question is heat in, so the water’s change is endothermic.

7. A trap first-timers fall into

First-timers often grab the first formula they remember, mix units (cm with m, minutes with seconds), or drop a minus sign. Write the formula in words first: “this equals that, because…”

Ntsako · fx-991ZA PLUS. Tap to calculate.